Radicals in Synthesis I
Methods and Mechanis
Volume Editor: Andreas Gansäuer
With contributions by
A. Barchuk · F. Brebion · D. Crich · K. Daajerg · V. Darmency
A. Gansäuer · M. Gerenkamp · S. Grimme · C. Mück-Lichtenfeld
P. Renaud · M.P. Sibi · D.-H. Suk ·H. Svith · J. Zimmerman · H. Zipse
Contents
Generation of Alkene Radical Cations by Heterolysis
of β-Substituted Radicals:
Mechani, Stereochemistry, and Applications in Synthesis
D.Crich·F.Brebion·D.-H.Suk . . . . . . . . . . . . . . . . . . . . . . 1
TheMechani of Epoxide Opening Through Electron Transfer:
Experiment and Theory in Concert
K. Daajerg · H. Svith · S. Grimme · M. Gerenkamp ·
C.Mück-Lichtenfeld·A.Gansäuer ·A.Barchuk . . . . . . . . . . . . . 39
Tin-Free Radical Reactionediated
by Organoboron Compounds
V.Darmency·P.Renaud . . . . . . . . . . . . . . . . . . . . . . . . . . 71
Enantioselective Radical Reactions
J.Zimmerman·M.P.Sibi . . . . . . . . . . . . . . . . . . . . . . . . . 107
Radical Stability – A Theoretical Perspective
H.Zipse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163
Author Index Volumes 251–263 . . . . . . . . . . . . . . . . . . . . . . 191
Subject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
Radicals in Synthesis II
ComplexMolecules
Volume Editor: Andreas Gansäuer
With contributions by
M. Albert · J.M. Cuerva · L. Fensterbank · S.G.Hansen
J. Justicia · E. Lacôte · M. Malacria · A.M. McGhee
J.L.Oller-López · J.E. Oltra · D. J. Procter · B. Quiclet-Sire
T. Skrydstrup · J. C.Walton · S. Z. Zard
Contents
Tandem Radical Reactions
M.Albert ·L.Fensterbank·E.Lacôte·M.Malacria . . . . . . . . . . . 1
Cp2TiCl in Natural Product Synthesis
J.M.Cuerva· J. Justicia· J.L.Oller-López· J.E.Oltra . . . . . . . . . . . 63
Radical Chemistry on Solid Support
A.M.McGhee·D.J.Procter . . . . . . . . . . . . . . . . . . . . . . . . 93
Modification of Amino Acids, Peptides, and Carbohydrates
Through Radical Chemistry
S.G.Hansen·T.Skrydstrup . . . . . . . . . . . . . . . . . . . . . . . . 135
Unusual Radical Cyclisations
J.C.Walton . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163
The Degenerative Radical Transfer of Xanthates and Related Derivatives:
An Unusually Powerful Tool for the Creation of Carbon–Carbon Bonds
B.Quiclet-Sire·S.Z.Zard . . . . . . . . . . . . . . . . . . . . . . . . . 201
Author Index Volumes 251–264 . . . . . . . . . . . . . . . . . . . . . . 237
Subject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 245
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