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楼主  发表于: 2006-09-04 16:37
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 利用EZ代理使用网络版的Combined Chemical Dictionary (CCD)

Combined Chemical Dictionary (CCD) :
利用ＥＺ找到：＂ChemNetBase＂不好意思借用一个ＥＺ来说明一下使用过程：http://ezproxy.lib.monash.edu.au/login
stwal1/1800916046s；在显示的数据库中找到ChemNetBase链接为：http://www.chemnetbase.com.ezproxy.lib.monash.edu.au/在＂Online Products"中打开＂Combined Chemical Dictionary (CCD) ＂
例如搜索:1,3-Propanediol 然后:选中"View Results In New Window"在打开的网页中双击＂１，３－porpanediol,9CL..."在新弹出的窗口中显示结果:1,3-Propanediol
Synonym(s) Trimethylene glycol
Chapman & Hall Number DFN74
CAS Registry Number 504-63-2
Linear Diagram HOCH2CH2CH2OH
Molecular Formula C3H8O2
Molecular Weight 76.095
Accurate Mass 76.052430
Percentage Composition C 47.35%; H 10.60%; O 42.05%
General Statement This isomer is sometimes referred to as *propylene glycol*, but the name normally means the 1,2-isomer, or a mixture of the two
Hazard and Toxicity LD50 (mus, orl) 4773 mg/kg. Fl. p. 74°, autoignition temp. 371/421°
Solubility Sol. H2O, EtOH, Et2O
Use / Importance Monomer for polyesters and polyurethanes
Biological Use / Importance Stimulator of glucose metaboli used in veterinary science e.g. for treatment of pregnancy toxaemia in sheep
Melting Point Mp -27°
Dissociation Constant pKa 1 15.10 (25°)
Partition Coefficient (Experimental) Log P -1.04 S (exp)
Boiling Point Bp 210.Bp 211° Bp12 109.Bp 110°
Density d204 1.06
Refractive Index n20D 1.4398
RTECS Accession Number TY2010000
Aldrich P5040-4
Fluka 81780
Sigma P3051
Derivative Dinitrate
View Structure
Chapman & Hall Number DFN75
CAS Registry Number 3457-90-7
Molecular Formula C3H6N2O6
Molecular Weight 166.09
Accurate Mass 166.022588
Percentage Composition C 21.69%; H 3.64%; N 16.87%; O 57.80%
Hazard and Toxicity Explodes at 107°
Physical Description Oil
Derivative Mono-Ac
View Structure
Synonym(s) 3-Acetoxy-1-propanol
Chapman & Hall Number DFN76
CAS Registry Number 36678-05-4
Molecular Formula C5H10O3
Molecular Weight 118.132
Accurate Mass 118.062995
Percentage Composition C 50.84%; H 8.53%; O 40.63%
Boiling Point Bp 202.5.Bp 204°
Derivative Di-Ac
View Structure
Synonym(s) 1,3-Diacetoxypropane
Chapman & Hall Number DFN77
CAS Registry Number 628-66-0
Molecular Formula C7H12O4
Molecular Weight 160.169
Accurate Mass 160.073560
Percentage Composition C 52.49%; H 7.55%; O 39.96%
Solubility Sol. H2O
Boiling Point Bp 209.Bp 210°
Derivative Monobenzoyl
View Structure
Chapman & Hall Number MQD05
CAS Registry Number 6946-99-2
Molecular Formula C10H12O3
Molecular Weight 180.203
Accurate Mass 180.078645
Percentage Composition C 66.65%; H 6.71%; O 26.64%
Boiling Point Bp12 163.Bp 164°
Derivative Dibenzoyl
View Structure
Chapman & Hall Number MQD06
CAS Registry Number 2451-86-7
Molecular Formula C17H16O4
Molecular Weight 284.311
Accurate Mass 284.104860
Percentage Composition C 71.82%; H 5.67%; O 22.51%
Physical Description Needles (petrol)
Melting Point Mp 60 - 61°
Derivative Bis(4-aminobenzoyl)
View Structure
Chapman & Hall Number KYL63
CAS Registry Number 57609-64-0
Molecular Formula C17H18N2O4
Molecular Weight 314.34
Accurate Mass 314.126658
Percentage Composition C 64.96%; H 5.77%; N 8.91%; O 20.36%
Physical Description Cryst.
Use / Importance Cross-linking agent for epoxy resins and polyurethanes
Melting Point Mp 124 - 127°
Derivative Bis(4-methylbenzenesulfonyl)
View Structure
Chapman & Hall Number MQQ67
CAS Registry Number 5469-66-9
Melting Point Mp 90 - 92°
Aldrich 31755-1
Derivative Mono-Me ether
View Structure
Synonym(s) 3-Methoxy-1-propanol
Chapman & Hall Number DFN78
CAS Registry Number 1589-49-7
Molecular Formula C4H10O2
Molecular Weight 90.122
Accurate Mass 90.068080
Percentage Composition C 53.31%; H 11.18%; O 35.51%
Hazard and Toxicity Skin irritant. Flammable, fl. p. 38° (oc)
Boiling Point Bp 153.15.Bp 153.2°
Derivative Me ether, formyl
View Structure
Chapman & Hall Number DFN80
Molecular Formula C5H10O3
Molecular Weight 118.132
Accurate Mass 118.062995
Percentage Composition C 50.84%; H 8.53%; O 40.63%
Boiling Point Bp 146.Bp 147°
Derivative Me ether, Ac
View Structure
Synonym(s) 1-Acetoxy-3-methoxypropane
Chapman & Hall Number DFN81
CAS Registry Number 41448-83-3
Molecular Formula C6H12O3
Molecular Weight 132.159
Accurate Mass 132.078645
Percentage Composition C 54.53%; H 9.15%; O 36.32%
Hazard and Toxicity Flammable, fl. p. 42°
Boiling Point Bp 162.Bp 163.5°
Derivative Di-Me ether
View Structure
Synonym(s) 1,3-Dimethoxypropane
Chapman & Hall Number MQD04
CAS Registry Number 17081-21-9
Molecular Formula C5H12O2
Molecular Weight 104.149
Accurate Mass 104.083730
Percentage Composition C 57.66%; H 11.61%; O 30.72%
Melting Point Mp -82°
Boiling Point Bp 106°
Derivative Mono-Et ether
View Structure
Synonym(s) 3-Ethoxy-1-propanol
Chapman & Hall Number DFN82
CAS Registry Number 111-35-3
Molecular Formula C5H12O2
Molecular Weight 104.149
Accurate Mass 104.083730
Percentage Composition C 57.66%; H 11.61%; O 30.72%
Hazard and Toxicity Mod. toxic
Solubility Misc. H2O
Boiling Point Bp 162.1.Bp 162.2°
Density d154 0.92
Refractive Index n20D 1.4167
Aldrich E740-1
Derivative Et ether, Ac
View Structure
Synonym(s) 1-Acetoxy-3-ethoxypropane
Chapman & Hall Number DFN83
CAS Registry Number 94825-54-4
Molecular Formula C7H14O3
Molecular Weight 146.186
Accurate Mass 146.094295
Percentage Composition C 57.51%; H 9.65%; O 32.83%
Hazard and Toxicity Skin irritant
Boiling Point Bp 174.5.Bp 175.5°
Density d154 0.96
Derivative Di-Et ether
View Structure
Synonym(s) 1,3-Diethoxypropane, 9CI
Chapman & Hall Number DFN84
CAS Registry Number 3459-83-4
Molecular Formula C7H16O2
Molecular Weight 132.202
Accurate Mass 132.115030
Percentage Composition C 63.60%; H 12.20%; O 24.20%
Boiling Point Bp 140.Bp 141°
Density d2525 0.84
Derivative Butyl ether
View Structure
Synonym(s) 3-Butoxy-1-propanol
Chapman & Hall Number HMY60
CAS Registry Number 29387-86-8
Molecular Formula C7H16O2
Molecular Weight 132.202
Accurate Mass 132.115030
Percentage Composition C 63.60%; H 12.20%; O 24.20%
Use / Importance Solvent
Boiling Point Bp13 81.Bp 85°
Density d 1.42
Refractive Index n25D 1.4238
Derivative Me-Ph ether
View Structure
Synonym(s) 1-Methoxy-3-phenoxypropane
Chapman & Hall Number DFN79
CAS Registry Number 61372-56-3
Molecular Formula C10H14O2
Molecular Weight 166.219
Accurate Mass 166.099380
Percentage Composition C 72.26%; H 8.49%; O 19.25%
Boiling Point Bp 230.Bp 231°
Derivative Di-Ph ether
View Structure
Synonym(s) 1,3-Diphenoxypropane
Chapman & Hall Number DFN85
CAS Registry Number 726-44-3
Molecular Formula C15H16O2
Molecular Weight 228.29
Accurate Mass 228.115030
Percentage Composition C 78.92%; H 7.06%; O 14.02%
Physical Description Leaflets (EtOH)
Melting Point Mp 61°
Boiling Point Bp 338.Bp 340°
Related CAS Registry Number(s) 10215-33-5 26264-14-2
References
Aldrich Library of FT-IR Spectra, 1st edn. , 1985 , 1 , 128A , (ir) ; Aldrich Library of FT-IR Spectra, 1st edn., 1, 223D,
Aldrich Library of 13C and 1H FT NMR Spectra , 1992 , 1 , 192B , (nmr) ; Aldrich Library of 13C and 1H FT NMR Spectra, 1, 339C, Aldrich Library of 13C and 1H FT NMR Spectra, 2, 1606C,
Aldrich Library of FT-IR Spectra: Vapor Phase , 1989 , 3 , 188C , (ir) ; Aldrich Library of FT-IR Spectra: Vapor Phase, 3, 294A,
Van Duzee, E.M., etal., J.A.C.S. , 1935 , 57 , 147 , (butyl ether)
Chitland, H.C., J.A.C.S. , 1946 , 68 , 680 , (butyl ether)
Adkins, H., etal., J.A.C.S. , 1948 , 70 , 3121 , (synth)
Brewster, J.H., J.A.C.S. , 1951 , 73 , 366 , (polyurethanes)
Korshak, V.V., etal., Zh. Obshch. Khim. , 1956 , 26 , 539 , (polyamides) ; J. Gen. Chem. USSR (Engl. Transl.), 26, 575,
Walborsky, H.M., etal., J.O.C. , 1962 , 27 , 2387 , (synth)
Sawodny, K.N., etal., Spectrochim. Acta A , 1967 , 23 , 799 , (ir)
Pihlaja, K., etal., Acta Chem. Scand. , 1969 , 23 , 715 , (synth)
van de Sande, C.C., etal., J.A.C.S. , 1975 , 97 , 4617 , (ms)
Ger. Pat. , 1979 , 2 853 175 , (bis-4-aminobenzoyl, synth, use) ; CA, 91, 157454c,
Grindley, T.B., etal., J. Carbohydr. Chem. , 1985 , 4 , 171 , (cmr)
Encyclopaedia of Reagents for Organic Synthesis , (ed. Paquette, L.A.), Wiley , 1995 , 6 , 4306-4307 , (use)
Thalladi, V.R., etal., Angew. Chem., Int. Ed. , 2000 , 39 , 918-922 , (cryst struct)
Patty's Ind. Hyg. Toxicol. (3rd Rev. edn.) , Vol. 2, Wiley , 1980 , 3862 , (tox)
Lewis, R.J., Sax's Dangerous Properties of Industrial Materials, 8th edn., Van Nostrand Reinhold , 1992 , EFG000 ; Sax's Dangerous Properties of Industrial Materials, 8th edn., Van Nostrand Reinhold, , MFL000, Sax's Dangerous Properties of Industrial Materials, 8th edn., Van Nostrand Reinhold, , PML250,





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