Catalysis of Organic Reactions (Chemical Industries)
By: Jr. John R. Sowa(Editor) IN: 0824727290
IN-13: 9780824727291
Publisher: CRC - 2005-03-30
Hardcover | 600 Pages
SynopsisIn these proceedings of the March 2004 conference, participants offer reviews of their research in catalysis as related to organic synthesis with special emphasis on processes with actual or potential applications in industry. Papers on catalytic hydrogenation includes topics such as the hydrogenation of Raney-type catalysts, anchored and supported hydrogenation catalysts, and the hydrogenation of substrates and renewable resources. The section on the conference's symposium on novel concepts and approaches to catalysis of organic reactions includes papers on combinatorial and parallel methods in catalyst design, and optimization and utilization, while the symposium on catalysts in organic synthesis yields papers on deprotection reactions and asymmetric catalysis.
Table of ContentsI Symposium on catalytic hydrogenation 11 2004 Murray Raney award : electrocatalytic hydrogenation of organic compounds at Raney metal electrodes : scope and limitations 3
2 Low pressure slurry hydrogenation process for the production of dimethylaminopropylamine using sponge Nickel catalyst 19
3 The conversion of ethanolamine to glycine salt over skeletal copper catalysts 27
4 Hydrogenation catalysis in a nylon recycle process 37
5 Hydrogenation of dodecanenitrile over Raney type and supported group VIII metal catalysts and effect of metal on selectivity 45
6 Highly efficient metal catalysts supported on activated carbon cloths 53
7 Anchored Wilkinson's catalyst 59
8 Carbon supported anchored homogeneous catalysts 65
9 Catalytic hydrogenation of cinnamaldehyde on pt/carbon catalysts : the effects of metal location, and dispersion on activity and selectivity 71
10 Para-substituted aniline hydrogenation over rhodium catalysts : metal crystallite size and catalyst pore size effects 77
11 Reductive alkylation during nitrobenzene hydrogenation over copper/silica 85
12 Hydrogenolysis of butyl acetate to butanol over naphtha reforming type catalysts in conventional and high throughput slurry phase reactors 91
13 New ways for the full hydrogenation of quinoline in mild conditions 101
14 Some recent developments in heterogeneous hydrogenation catalysts for organic synthesis 111
15 Hydrogenation of nitrile butadiene rubber catalyzed by [Ir(COD)py(PCy[subscript 3])]PF[subscript 6] 125
16 Catalytic hydrogenation and hydrogenolysis of lignin model compounds using in-situ, water-soluble Ru/P(CH[subscript 2]OH)[subscript 3] systems 135
17 Catalytic preparation of pyrrolidones from renewable resources 145
18 Hydrogenation of glutamic acid to value added products 155
19 Catalytic hydrogenolysis of 5-carbon sugar alcohols 165
II Symposium on novel concepts and approaches to catalysis of organic reactions 17520 Combinatorial approaches for new catalyst discovery : the first homogeneous catalysts derived from combinatorial technologies for a variety of cross-coupling reactions 177
21 High throughput experiments in design and optimization of catalytic package for direct synthesis of diphenylcarbonate 185
22 Rapid optimization of hydrogenation process variables by combining experimental design and parallel reactors 195
23 Design and parallel synthesis of new oxidative dehydrogenation catalysts 201
24 Nanocluster-based cross-coupling catalysts : a high-throughput approach 211
25 Do you need a transition metal for biaryl synthesis?
26 Enzyme-like acceleration in catalytic anti-Markovnikov hydration of alkynes to aldehydes 227
27 An enzyme-like mechani involving bifunctional Ru catalysts 237
28 Activation of dendrimer encapsulated Pt nanoparticles for heterogeneous catalysts 243
29 Avada - a new green process for the production of ethyl acetate
30 A catalytic distillation process for the one step synthesis of methyl isobutyl ketone from acetone : liquid phase kinetics of the hydrogenation of mesityl oxide 261
31 A strategy for the preparation of isolated organometallic catalysts on silica supports - towards single-site solid catalysts 267
32 Ring opening of naphthenes for clean diesel fuel production 279
33 The use of copper catalysts in the hydrogen transfer reduction of 4-Tert-butylcyclohexanone 293
34 The effect of ultrasound on the isomerization versus reduction reaction pathways in the hydrogenation of 3-buten-2-ol and 1,4-pentadien-3-ol and Pd-black 303
35 Lessons learned : batch processing, scaleup from laboratory to plant 313
III Symposium on acid-base catalysis 32636 Improved solid-acid catalysis for sustainable, high 2-phenyl, LAB production 327
37 Recent advances in thermally stable resins for olefin hydration 337
38 Enhancement of regioselectivity in the gas-phase methylation of m-cresol with multifunctional heterogeneous catalysts 347
39 Hydroxymethylation of 2-methoxyphenol with formaldehyde to yield vanillic alcohols : a comparison between homogeneous and heterogeneous acid catalysis 357
40 The aldol condensation of acetone over a CsOH/SiO[subscript 2] solid base catalyst 363
41 Solid acid catalysed esterification of amino acids and other bio-based acids 373
42 One pot transformation of geraniol into citronellol and menthol over Cu/Al[subscript 2]O[subscript 3] 379
43 Investigation of chlorine substitution effects in the Claisen-Schmidt condensation of 2'-hydroxyacetophenone with chlorobenzaldehydes over MgO 385
IV Symposium on catalytic oxidation 39244 The effect of single metal variation in Mo-V-Nb-W/Al[subscript 2]O[subscript 3] system on propane selective oxidation 393
45 Partial oxidation of propylene over supported rhodium catalysts 403
46 The effect of biuth promotion on the selective oxidation of alcohols using platinum catalysts 413
47 Preparation and activity of a V-Ti/Silica catalyst for olefin epoxidation 423
48 Aerobic formaldehyde oxidation under mild conditions mediated by Ce-containing polyoxometalates 429
V Symposium on catalysis in organic synthesis 43449 2004 Paul N. Rylander award : palladium-catalyzed annulation and migration reactions 435
50 New palladium-catalysed processes for the synthesis of selectively substituted aromatics 449
51 O-acylphosphites : new and promising ligands for isomerizing hydroformylation 459
52 The synthesis of carbamate from the reductive carbonylation of nitrobenzene over Pd-based catalysts 471
53 Microwave synthesis in the Suzuki-Miyaura cross coupling reaction with Pd/C catalysts 479
54 Improved catalyst for the removal of carbobenzyloxy protective groups 485
55 The effect of N-containing modifiers on the deprotection of a carbobenzyloxy protected amino acid 493
56 Selective debenzylation in the presence of aromatic chlorine on Pd/C catalysts : effects of catalyst types and reaction kinetics 499
57 A comparison between the homogeneous and the anchored rhodium skewphos catalyst 513
58 Asymmetric heck reactions using dipeptido phosphinite metal complexes 519
59 Enantioselective hydrogenations of exo- and endocyclic C=C double bond with highly mesoporous carbon supported Pd 525
60 Influence of achiral tertiary amines on the enantioselective hydrogenation of [alpha],[beta]-diketones over cinchonidine-Pt/Al[subscript 2]O[subscript 3] catalyst 535
61 Enantioselective hydrogenation of diketones on Pt supported catalysts 541
62 Enantioselective hydrogenation of [alpha],[beta]-unsaturated acids or esters 547
63 The effects of Pt/Al[subscript 2]O[subscript 3] structure and stability on the O-methyl-10,11-dihydrocinchonidine modified enantioselective hydrogenation of activated ketones 553
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